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Beilstein J. Org. Chem. 2015, 11, 446–468, doi:10.3762/bjoc.11.51
Graphical Abstract
Scheme 1: Selective O-acetylation of hydroxyamino acids with acetic anhydride in perchloric acid-acetic acid ...
Scheme 2: Selective O-acetylation of L-tyrosine as reported by Bretschneider and Biemann in 1950 [13].
Scheme 3: Selective O-acetylation of L-serine in acetic acid saturated with hydrogen chloride as reported by ...
Scheme 4: Chemoselective O-acetylation of hydroxyamino acids with acetyl chloride in hydrochloric acid–acetic...
Scheme 5: Chemoselective O-acylation of hydroxyamino acids with acyl chlorides in anhydrous trifluoroacetic a...
Scheme 6: Chemoselective O-acylation of hydroxyproline with acyl chlorides or carboxylic anhydrides in methan...
Scheme 7: Chemoselective O-acetylation of L-DOPA as reported by Fuller, Verlander and Goodman in 1978 [35].
Scheme 8: Chemoselective O-acylation of L-tyrosine as reported by Huang, Kimura, Bawarshi-Nassar and Hussain ...
Scheme 9: Preparation of proline amphiphiles or acrylic proline monomers (for macromolecular synthesis) by ch...
Scheme 10: Preparation of amphiphilic organocatalysts from serine, threonine and cysteine by chemoselective O-...
Scheme 11: Preparation of amphiphilic proline organocatalysts by chemoselective O-acylation with acyl chloride...
Scheme 12: Amphiphilic organocatalysts prepared from hydroxyamino acids and isosteviol by chemoselective O-acy...
Scheme 13: Preparation of acrylic proline precursors for polymeric organocatalysts by chemoselective O-acylati...
Scheme 14: Conversion of trans-4-hydroxy-L-proline to cis-4-hydroxy-D-proline·HCl and subsequent chemoselectiv...
Scheme 15: Some examples of chemoselective O-acylation of amino alcohols under acidic reaction conditions repo...
Scheme 16: An assembly of chiral acrylic building blocks useful in the synthesis of polymer-supported diphenyl...
Scheme 17: The chemoselective pentaacetylation of D-glucamine under acidic reaction conditions [95].
Beilstein J. Org. Chem. 2012, 8, 1126–1133, doi:10.3762/bjoc.8.125
Figure 1: Thiol, alkene and organocatalyst building blocks for combined bead polymerization and Cinchona orga...
Scheme 1: Combined bead polymerization and Cinchona organocatalyst immobilization by thiol–ene addition.